化工英文文献翻译ThesynthesisofH2tsalamoisshowninScheme1.Thereactionofthethiosalicylaldehyde5b,12,13with1,2-bis(aminooxy)ethane14affordedtheH2tsalamoin47%yieldascolorlesscrystals.15H2tsalamoisremarkablystablebothin-查询网问答

化工英文文献翻译ThesynthesisofH2tsalamoisshowninScheme1.Thereactionofthethiosalicylaldehyde5b,12,13with1,2-bis(aminooxy)ethane14affordedtheH2tsalamoin47%yieldascolorlesscrystals.15H2tsalamoisremarkablystablebothin

更新时间：2024-04-28 04:23:29

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化工英文文献翻译

ThesynthesisofH2tsalamoisshowninScheme1.The

reactionofthethiosalicylaldehyde5b,12,13with1,2-bis(aminooxy)

ethane14affordedtheH2tsalamoin47%yieldascolorless

crystals.15H2tsalamoisremarkablystablebothinthesolid

stateandinsolution.The1HNMRspectrumofH2tsalamo

inCDCl3wasnotchangedevenafterseveraldays.15Thus,theoximeligandH2tsalamoismuchmorestablethanH2-

tsalen.However,H2tsalamoinhighlydilutedsolution

decomposedveryslowlyunderaerobicconditionsprobably

duetoautoxidation.Thus,H2tsalamoislessstablethanH2-

salamo.

H2tsalamoreactedwithnickel(II)acetateindichloromethane/

methanoltoaffordthecorrespondingnickel(II)

complexasdarkbrowncrystalsin67%yield.Elemental

analysisisconsistentwiththeformulaofthemononuclear

complex[Ni(tsalamo)].16Apeakatm/z)387.98[Ni-

(tsalamo)]+intheESI-massspectrum(FiguresS1andS2,

SupportingInformation)alsosupportsthemononuclear

structure.Furthermore,inthe1HNMRspectrumofthe

nickel(II)complexinCDCl3sixsharpsignalsappeared,

indicatingtheexclusiveformationofasymmetricaland

diamagneticcomplex.Intheelectronicabsorptionspectra,

d-dtransitionwasobservedat620nm()260)andan

LMCTbandwasobservedat382nm()6000)(Figure

1),whicharecharacteristicoflow-spinsquareplanarnickel-

(II)complexeswithN2S2coordinationspheres.17Thissimple

andeasypreparationofthemetalcomplexwithanN2S2

chelatecontrastswiththelaborioussynthesisusingthe

correspondingimineanalogueH2tsalen.4,6-10

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　　我翻译的. 　　你觉得可以的话多少给点. 　　如有错还请多包含. 　　合成的H2tsalamo计划1所示.该　　在thiosalicylaldehyde5b,反应12,131,2双（aminooxy）　　ethane14给予47％的无色产生H2tsalamo 　　crystals.15H2tsalamo是非常稳定都在固体　　国家和解决方案.该H2tsalamo核磁共振谱　　在氘代氯仿是没有改变,甚至经过几次days.15因此,肟配体H2tsalamo更稳定比H-2A火箭　　tsalen.然而,在高度稀释的溶液H2tsalamo 　　分解很慢好氧条件下可能　　由于自氧化.因此,H2tsalamo稳定性较差比H-2A火箭　　萨拉莫. 　　H2tsalamo与镍反应（二）醋酸二氯甲烷/ 　　甲醇负担相应的镍（II）　　复杂,67％的收益率在深褐色的结晶.元素　　分析与单核公式一致　　配合物[Ni（tsalamo）].16在米高峰/z）的387.98[镍　　（tsalamo）]在电喷雾质谱（图S1和S2+, 　　支持信息）也支持单核　　结构.此外,在核磁共振谱　　镍（II）在氘代氯仿6尖锐复杂的信号出现, 　　说明专用形成一个对称的, 　　反磁性复杂.在电子吸收光谱, 　　日日的过渡是在620nm处观察（?）260）和1 　　电荷转移带,观察到382纳米（?）6000）（图　　1）,它是低自旋特性平面方形镍　　（二）与N2S2协调spheres.17这个简单的复合物　　和容易制备的金属配合物1N2S2 　　螯合物对比与使用合成吃力　　相应的亚胺模拟H2tsalen.4,6-10